Diterpenoids from isodon eriocalyx

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A Customizable Approach for the Enzymatic Production and Purification of Diterpenoid Natural Products
07:59

A Customizable Approach for the Enzymatic Production and Purification of Diterpenoid Natural Products

Published on: October 4, 2019

Chen1, Yue, Chen

  • 1Shanghai Institute of Materia Medica, Academia Sinica, Shanghai 200031, People's Republic of China, Laboratory of Phytochemistry, Kunming Institute of Botany, Academia Sinica, Kunming 650204, People's Republic of China, and Department of.

Journal of Natural Products
|May 29, 1999
PubMed

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Preparation of Diols and Pinacol Rearrangement01:57

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Compounds bearing two hydroxyl groups are known as diols. When the hydroxyl groups are located on adjacent carbon atoms, the diols are called vicinal diols or glycols. Under acidic conditions, vicinal diols undergo a specific reaction called pinacol rearrangement.
The reaction begins with transferring a proton from the acid catalyst to one of the hydroxyl groups, producing an oxonium ion.