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The red form of [Re(phen)(CO)3(H2O)]-CF3SO3.H2O
W B Connick1, A J Di Bilio, W P Schaefer
1Beckman Institute, California Institute of Technology, Pasadena 91125, USA. bill.connick@uc.edu
Abstract:
The coordination geometry of the cations in the red form of aquatricarbonyl(1,10-phenanthroline-N,N')rhenium(I) trifluoromethanesulfonate hydrate, [Re(C12H8N2)(CO)3-(H2O)]CF3SO3.H2O, is approximately octahedral, with a facial arrangement of the linearly coordinated carbonyl ligands. The phenanthroline (phen) ligands interleave to form a columnar pi-stacked structure.
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