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Unusual Contact-Line Dynamics of Thick Films and Drops
Veretennikov1, Agarwal, Indeikina
1Department of Chemical Engineering, University of Notre Dame, Notre Dame, Indiana, 46556
Journal of Colloid and Interface Science
|July 27, 1999
Summary
Macroscopic spinning drops and gravity-driven films exhibit novel contact-line and fingering dynamics. These phenomena arise from complex interfacial shapes and force balances, leading to unexpected behaviors like viscosity-dependent finger speed.
Area of Science:
- Fluid dynamics
- Surface science
- Physics of interfaces
Background:
- Understanding fluid behavior at macroscopic scales is crucial for various applications.
- Contact-line dynamics and fingering instabilities are complex phenomena influenced by multiple forces.
Purpose of the Study:
- To investigate novel phenomena in contact-line and fingering dynamics of macroscopic spinning drops and gravity-driven films.
- To analyze the influence of external body forces, capillarity, viscosity, and intermolecular forces on fluid behavior.
- To explore the mechanisms behind finger development and spreading dynamics.
Main Methods:
- Experimental analysis of macroscopic spinning drops and gravity-driven films.
- Theoretical analysis of interfacial shapes and dynamics.
- Investigation of fluid properties like viscosity and wetting behavior.
Main Results:
- Macroscopic films exhibit multi-valued interfacial shapes near the contact line due to force balances.
- A single finger develops on partially wetting spinning drops via a distinct mechanism.
- Glycerine finger speed increases with viscosity at high viscosity and low rotation frequencies.
- Completely wetting fluids spread faster on dry surfaces than prewetted ones.
- Prewetted films suppress fingering in gravity-driven flow and spin coating.
Conclusions:
- Macroscopic fluid interfaces display rich and unexpected dynamics governed by a interplay of forces.
- The study reveals unique fingering mechanisms and spreading behaviors not observed in microscopic systems.
- Findings offer insights into fluid behavior relevant to coating, printing, and other industrial processes.