The First Synthesis of Organic Diselenolates: Application to the Synthesis of Diorganyl Diselenides
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Updated: Aug 10, 2026

Synthesis of Nine-atom Deltahedral Zintl Ions of Germanium and their Functionalization with Organic Groups
Published on: February 11, 2012
1Laboratoire de Chimie Organique de Synthèse, Département de Chimie Facultés Universitaires Notre-Dame de la Paix, 61 rue de Bruxelles, B-5000 Namur (Belgium).
Abstract:
The addition of elemental selenium to organolithium compounds 1 or organic selenates 2 gives organic diselenolates 3. The reactions proceed by the insertion of two selenium atoms into the carbon-metal bonds or of one selenium atom into a selenolate. Evidence for the existence of n-butyldisilenol has also been obtained.
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