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1Institut für Anorganische Chemie der Universität, Greinstrasse 6, D-50939 Köln (Germany).
Angewandte Chemie (International Ed. in English)
|July 30, 1999
Abstract:
The long-postulated reactive intermediates of polar fluoride-inititated trifluoromethylations with Me(3)SiCF(3) (see scheme) were identified by NMR spectroscopy as [Me(3)Si(CF(3))F](-) and [Me(3)Si(CF(3))(2)](-)(.)