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Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
Published on: March 20, 2014
Electronic Communication in C(4)-Bridged Binuclear Complexes with Paramagnetic Bisphosphane Manganese End Groups
Kheradmandan1, Heinze, Schmalle
1Department of Inorganic Chemistry, University of Zürich, Winterthurerstrasse 190, CH-8057 Zürich (Switzerland).
Angewandte Chemie (International Ed. in English)
|July 30, 1999
Summary
Linear manganese complexes with unsaturated carbon chains show electron communication, crucial for developing conductive polymers and nonlinear optical (NLO) materials.
Area of Science:
- Organometallic Chemistry
- Materials Science
Background:
- Linear, unsaturated carbon chains bridged manganese complexes are key building blocks.
- These complexes are investigated in various oxidation states (n=0-2).
Purpose of the Study:
- To synthesize and characterize novel manganese complexes.
- To investigate the electronic properties of the carbon chain bridge.
- To establish the potential of these complexes for conducting polymers and NLO materials.
Main Methods:
- Spectroscopic analysis was employed to study the complexes.
- X-ray structure determination provided detailed structural insights.
Main Results:
- All investigated oxidation states (n=0-2) were successfully characterized.
- Analytical data confirmed electron communication across the C(4) carbon chain.
- This electron communication is a prerequisite for desired material properties.
Conclusions:
- The studied manganese complexes exhibit electronic properties suitable for advanced materials.
- These findings pave the way for the development of new conducting polymers and NLO materials.
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