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The First Efficient Hydroaminomethylation with Ammonia: With Dual Metal Catalysts and Two-Phase Catalysis to Primary
1Technische Universität München, Lichtenbergstrasse 4, D-85747 Garching (Germany).
Angewandte Chemie (International Ed. in English)
|August 24, 1999
Abstract:
Primary and unbranched secondary amines are obtained by the highly selective hydroaminomethylation of olefins with ammonia [Eq. (a)]. The selectivity is readily controlled with a new dual Rh/Ir catalyst in a two-phase system.