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Highly Active Ruthenium Catalysts for Olefin Metathesis: The Synergy of N-Heterocyclic Carbenes and Coordinatively
1Anorganisch-chemisches Institut der Technischen Universität München, Lichtenbergstrasse 4, D-85747 Garching (Germany).
Angewandte Chemie (International Ed. in English)
|August 24, 1999
Abstract:
Two N-heterocyclic carbene ligands at once may be one too many, at least if you intend to have highly active ruthenium catalysts for olefin metathesis. Density functional calculations recommend the replacement of the second carbene ligand in the successful ROMP catalysts 1 by coordinatively more labile ligands as in 2 or 3. In both cases, the catalytic activity is greatly improved.