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C(6)F(5)XeCl and

Frohn1, Schroer, Henkel

  • 1Fachgebiet Anorganische Chemie der Universität, D-47048 Duisburg (Germany).

Angewandte Chemie (International Ed. in English)
|October 3, 1999
PubMed
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Researchers synthesized novel xenon(II) chlorine compounds, C(6)F(5)XeCl and [(C(6)F(5)Xe)(2)Cl][AsF(6)], with high yields. These organo xenon compounds exhibit thermal instability, decomposing into known products.

Area of Science:

  • Inorganic Chemistry
  • Organometallic Chemistry
  • Noble Gas Chemistry

Background:

  • Xenon, a noble gas, was historically considered inert.
  • Recent advances have enabled the synthesis of xenon compounds.
  • Organoxenon compounds offer unique chemical properties.

Purpose of the Study:

  • To synthesize and characterize novel organoxenon(II) chlorine compounds.
  • To investigate the thermal stability and decomposition pathways of these new compounds.

Main Methods:

  • Synthesis of C(6)F(5)XeCl via reaction of pentafluorophenyl precursors with xenon difluoride.
  • Preparation of [(C(6)F(5)Xe)(2)Cl][AsF(6)] using a salt metathesis reaction.
  • Thermal decomposition studies to determine stability limits and products.

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Main Results:

  • High yields (85% and 91%) of isolable C(6)F(5)XeCl and [(C(6)F(5)Xe)(2)Cl][AsF(6)] were achieved.
  • C(6)F(5)XeCl decomposes vigorously at 36°C, yielding C(6)F(5)Cl and Xe.
  • [(C(6)F(5)Xe)(2)Cl][AsF(6)] decomposes at 100°C, producing C(6)F(5)Cl, C(6)F(6), and [C(6)F(5)Xe][AsF(6)].

Conclusions:

  • Novel organoxenon(II) chlorine compounds have been successfully synthesized.
  • These compounds demonstrate significant thermal instability, providing insights into xenon-carbon bond reactivity.
  • The decomposition products confirm the proposed structures and reactivity patterns.