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Updated: Aug 1, 2026

07:50
Electrophysiology of Scorpion Peg Sensilla
Published on: April 13, 2011
The Sting of the Scorpion: A Metallaboratrane
1Department of Chemistry, Imperial College of Science, Technology, and Medicine, South Kensington, London SW7 2AY (UK).
Angewandte Chemie (International Ed. in English)
|October 3, 1999
Abstract:
An unprecedented intramolecular B-H activation of a hydrotris(2-sulfanyl-1-methylimidazolyl)borate ligand coordinated to ruthenium has provided the first example of metallaboratranes. The remarkable ease with which the ruthenaboratrane 1 forms relative to the case with a hydrotris(pyrazolyl)borate ligand is a consequence of the lability of the chelation and the increased ring size of the chelates.
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