Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Videos

The First Bismuth Phosphide Complex:

Beswick1, Choi, Hopkins

  • 1Chemistry Department, University of Cambridge, Lensfield Road, Cambridge CB2 1EW (UK).

Angewandte Chemie (International Ed. in English)
|December 14, 1999
PubMed
Summary
This summary is machine-generated.

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

On the Epidemiology of Cape Colony and Natal in 1865.

Transactions. Epidemiological Society of London·2018
Same author

Cushing's syndrome associated with a chemodectoma and a carcinoid tumour.

Clinical endocrinology·2017
Same author

Correction. 9-Cis retinoic acid promotes lymphangiogenesis and enhances lymphatic vessel regeneration: therapeutic implications of 9-Cis retinoic acid for secondary lymphedema.

Circulation·2015
Same author

Functional studies of transcription factors involved in plant defenses in the genomics era.

Briefings in functional genomics·2015
Same author

NLA symposium on familial hypercholesterolemia. Question-and-answer session.

Journal of clinical lipidology·2010
Same author

[Carcinoma of the descending colon with subphrenic abscess perforating into a bronchus].

Guthrie Clinic bulletin·2010

The first structurally characterized bismuth phosphide complex was synthesized. Steric hindrance prevents molecular rearrangement in this thermally unstable compound.

Area of Science:

  • Organometallic Chemistry
  • Inorganic Chemistry
  • Materials Science

Background:

  • Bismuth phosphide complexes are underexplored in structural chemistry.
  • Understanding the structural and electronic properties of bismuth-containing compounds is crucial for developing new materials.

Purpose of the Study:

  • To synthesize and structurally characterize a novel bismuth phosphide complex.
  • To investigate the structural dynamics and stability of the synthesized compound.

Main Methods:

  • Reaction of tris(dimethylamino)bismuth, [Bi(NMe(2))(3)], with lithium tert-butylphosphide, [tBuPHLi], in a 1:3 ratio.
  • Crystallization from tetrahydrofuran/hexane solvent mixture.
  • X-ray diffraction analysis to determine the molecular structure.

Related Experiment Videos

Main Results:

  • Isolation and structural characterization of the first bismuth phosphide complex.
  • The complex exhibits a pseudo-trigonal bipyramidal geometry around the bismuth center.
  • Significant steric bulk from tert-butyl groups prevents Berry pseudorotation.

Conclusions:

  • The study reports the first structural characterization of a bismuth phosphide complex.
  • Steric factors play a critical role in stabilizing the complex and preventing dynamic rearrangements.
  • This work opens avenues for exploring novel bismuth-phosphorus chemistry and materials.