Interstellar molecules. Conversion Of C(3)O(-) to C(3)O in the gas phase

¹Department of Chemistry, The University of Adelaide, South Australia, 5005.

Rapid Communications in Mass Spectrometry : RCM

|November 5, 1999

Abstract:

Neutral C(3)O has been prepared by collision induced neutralisation of the precursor radical anion formed by the reaction (-)C identical withC-CO-OEt --> C(3)O(-) + EtO(). The similar neutralisation reionisation ((-)NR(+)) and charge reversal (CR) spectra of C(3)O(-) indicate that the potential surfaces of C(3)O and C(3)O(+) show favourable vertical Franck-Condon overlap. This suggests that the bond connectivities of anion, neutral and cation C(3)O are the same. Copyright 1999 John Wiley & Sons, Ltd.

Related Experiment Videos

Interstellar molecules. Conversion Of C(3)O(-) to C(3)O in the gas phase

Related Concept Videos

Development of engineered cells for implantation in gene therapy.

A mass spectrometry study of XCO+, X=Si, Ge: is SiCO+ a main group carbonyl? Comments on the bonding in ground state SiCO and the

alpha-Thalassemia Subtyping and the Detection of Silent Mutations by High-Resolution Fragment Analysis and DNA Sequencing.

Detection and Excretion Profile of Retatrutide in Human Plasma and Urine by LC-HRMS: Implications for Antidoping Analysis.

Stable Isotope Analysis (δ13C, δ15N and δ18O) of Killer Whale Dentine: Evaluating Treatment Methods and Establishing Best Practices.

Exploring the Mechanism of Zhigancao Decoction in the Treatment of Chronic Heart Failure via Modulation of Oxidative Stress.

Advances in the Design and Functionality of a Compact Multi-Reflecting Time-of-Flight Mass Spectrometer.

Exploratory Measurements of Singly Substituted and Clumped Isotopologues in Iodate Using Electrospray Ionization Mass Spectrometry.

Chemical Profiling by UHPLC-MS/MS and In Vitro Antioxidant, Antimicrobial, and Cytotoxic Properties of Lepidoceras peruvianum Kuijt Leaves and Fruits.

Uncatalyzed Guanosine Phosphorylation under Potentially Prebiotic Conditions.

Curvature- and pH-governed kinetics of electrocatalytic NO reduction on rare-earth single-atom catalysts: a DFT and constant-potential study.

Impact of Water Composition on Coffee Sensory Properties: A Comprehensive Analysis.

Windmill-Type π-Extension Within Donor Moiety of Covalent Organic Framework Boosts Overall Photocatalytic Hydrogen Peroxide Production.

Contact-Electrification Induced Electromagnetic Radiation and Charge Polarization Drive Spontaneous Microdroplet Interfacial Reactions.

Influence of sample positioning and solution volume on distinguishing sonolysis from piezocatalysis in ultrasonic dye degradation.

Related Experiment Videos

Interstellar molecules. Conversion Of C(3)O(-) to C(3)O in the gas phase

Abstract:

Related Concept Videos

Related Articles