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Characterization of sinapyl derivatives in pineapple (Ananas comosus [L.] Merill) juice
1Department of Food Science and Technology and Department of Biochemistry and Biophysics, Oregon State University, Corvallis, Oregon 97331, USA.
Abstract:
Three previously unidentified phenolic compounds were found in pineapple (Ananas comosus [L.] Merill) juice in substantial concentrations and were isolated by semipreparative reverse phase HPLC. The structures were elucidated from UV spectra, acid hydrolysis, and subsequent amino acid analysis, mass spectrometry, and two-dimensional NMR spectroscopy. The compounds are identified as S-sinapyl-L-cysteine, N-L-gamma-glutamyl-S-sinapyl-L-cysteine, and S-sinapylglutathione.

