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Transition Metal Induced Pentamerization of a Phosphaalkyne
1Institut für Anorganische Chemie der Universität, D-76128 Karlsruhe (Germany).
Angewandte Chemie (International Ed. in English)
|November 11, 1999
Abstract:
The metalla-norbornadiene complex 1, extended by two phosphaalkyne units in the 1,4-position, is formed by an unprecedented pentamerization of the phosphaalkyne MesC identical withP (Mes=2,4,6-Me(3)C(6)H(2)) in the coordination sphere of the transition metal complex [W(CO)(5)(thf)].