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Novel U-Shaped Systems Containing an Imide-Functionalized Cleft for the Study of Solvent-Mediated Electron Transfer
1School of Chemistry, University of New South Wales, Sydney, N.S.W., 2052 (Australia).
Angewandte Chemie (International Ed. in English)
|November 11, 1999
Abstract:
A solution to the vexing problem of investigating solvent-mediated electron transfer under conditions of frozen solvent motion may be at hand with the synthesis of novel U-shaped systems such as 1 (R=CO(2)Me) and 2 (R=CH(2)OMe), in which the imide-functionalized cleft provides the point of attachment of the "solvent" molecule, either covalently or by hydrogen bonding.
