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Isolation, characterization, and biological activity of naphthoquinones from Calceolaria andina L
B P Khambay1, D Batty, M Cahill
1Jodrell Laboratory, Royal Botanic Gardens, Kew, Surrey, United Kingdom. Bhupinder.khambay@bbscr.ac.uk
Abstract:
Two compounds recognized as responsible for the insecticidal activity of extracts of Calceolaria andina L. (Scrophulariaceae) have been isolated and characterized as 2-(1, 1-dimethylprop-2-enyl)-3-hydroxy-1,4-naphthoquinone and the corresponding acetate, 2-acetoxy-3-(1,1-dimethylprop-2-enyl)-1, 4-naphthoquinone. Their activities against 29 pest species and 9 beneficial species of arthropod from a total of 11 orders have been determined. Activities against homopteran and acarine species are of the same order as those of established pesticides, and, significantly, no cross-resistance is observed for strains resistant to established classes of insecticide. Mammalian toxicities are low.