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Identifying new volatile compounds in toasted oak.

I Cutzach1, P Chatonnet, R Henry

  • 1Groupement Interproducteurs Collioure-Banyuls, GICB, Banyuls/MER, Comité Interprofessionnel des Vins Doux Naturels, CIVDN, F-66300 Tresserre at the Bordeaux Faculty of Enology, Seguin-Moreau SA. Isabelle.Cutzach@oenologie.u-bordeaux2.fr

Journal of Agricultural and Food Chemistry
|November 24, 1999
PubMed
Summary

Researchers identified three new aroma compounds in toasted oak used for wine barrels. These compounds, including hydroxymaltol, may form from sugar pyrolysis or Maillard reactions during the toasting process.

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Area of Science:

  • Food Chemistry
  • Organic Chemistry
  • Wood Science

Background:

  • Toasting oak for wine barrels creates numerous volatile compounds.
  • Understanding these compounds is crucial for wine aging and flavor development.

Purpose of the Study:

  • Identify novel volatile, odorous compounds in toasted oak.
  • Investigate the formation pathways of these aroma compounds.

Main Methods:

  • High-performance gas chromatography with olfactory detection.
  • Gas chromatography-mass spectrometry and infrared spectrometry.
  • Nuclear Magnetic Resonance (RMN) analysis.

Main Results:

  • Three new volatile odorous compounds were identified: hydroxymaltol, 2,5-furanedicarbaldehyde, and furylhydroxymethyl ketone.

Related Experiment Videos

  • These compounds were detected in toasted oak extracts.
  • Acetylformoine was found in heated sugar/amino acid mixtures but not in toasted oak.
  • Conclusions:

    • Hydroxymaltol, 2,5-furanedicarbaldehyde, and furylhydroxymethyl ketone are key aroma contributors in toasted oak.
    • Their formation likely involves direct sugar pyrolysis or Maillard reactions.
    • The absence of acetylformoine in oak suggests specific reaction conditions during toasting.