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The performance and kinetic study of membrane anaerobic system in treating POME. Palm oil mill effluent
L S Lai1, A Fakhru'l-Razi, A Idris
1Faculty of Engineering, UPM.
Abstract:
The application of the three known kinetic models on MAS (membrane anaerobic system) process treating the POME and the overall MAS treatment efficiency were investigated. The MAS consists of a cross-flow ultrafiltration membrane (Model Micro 240) for solid-liquid separation. Six steady states were attained over a range of mixed liquor suspended solids of 12,681 - 30,460 mg/l. The study showed a good fitting of the Monod Model (91.1%), Contois Model (98.5%) and Chen and Hashimoto Model (95%) for the MAS treating raw POME at organic loadings between 1.5 kgCOD/m3/d to 6.5 kgCOD/m3/d. The growth yield coefficient, Y, was found to be 0,604 kg VSS/kgCOD while the specific microorganism decay rate was 0.099 day(-1). The k values were in the range of 0,242 to 0.425 mg COD/mg VSS.d and the microm values were between 0.145 to 0.257 day(-1). Throughout the study, the removal efficiency of COD was 83.2 to 97.97%. The methane production rate was between 0.262 to 0.473 l/g-COD-utilised/d. The MAS treatment efficiency was greatly affected by SRT and OLRs. In the study, membrane fouling and polarization at the membrane surface played a significant role in the formation of the strongly attached cake layer limiting membrane permeability
Insights
This study evaluated kinetic models for membrane anaerobic systems treating palm oil mill effluent (POME). The Contois model best described the process, achieving high COD removal and methane production.
Area of Science:
- Environmental Engineering
- Biotechnology
- Wastewater Treatment
Background:
- Palm oil mill effluent (POME) poses significant environmental challenges.
- Membrane anaerobic systems (MAS) offer a potential solution for POME treatment.
- Understanding kinetic models is crucial for optimizing MAS performance.
Purpose of the Study:
- To investigate the applicability of three kinetic models (Monod, Contois, Chen and Hashimoto) for MAS treating POME.
- To evaluate the overall treatment efficiency of the MAS process.
- To determine key kinetic parameters and their influence on performance.
Main Methods:
- Utilized a cross-flow ultrafiltration membrane (MAS) for solid-liquid separation.
- Operated the MAS at varying organic loading rates (OLRs) and mixed liquor suspended solids (MLSS).
- Applied Monod, Contois, and Chen and Hashimoto models to experimental data.
Main Results:
- The Contois model demonstrated the best fit (98.5%) for MAS treating raw POME.
- COD removal efficiency ranged from 83.2% to 97.97%.
- Methane production rates were between 0.262 to 0.473 l/g-COD-utilised/d, influenced by SRT and OLRs.
- Membrane fouling significantly impacted permeability.
Conclusions:
- Kinetic models, particularly the Contois model, accurately describe MAS performance for POME treatment.
- MAS is an effective technology for POME treatment, yielding high COD removal and methane production.
- Process parameters like SRT and OLRs, along with membrane fouling, are critical for MAS efficiency.
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