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Updated: Jul 31, 2026

Metal-free Synthesis of Ynones from Acyl Chlorides and Potassium Alkynyltrifluoroborate Salts
Published on: February 24, 2015
[Utilization of detoxification products of yperite-lewisite mixtures]
A M Boronin1, V G Sakharovskiĭ, I T Ermakova
1Skryabin Institute of Biochemistry and Physiology of Microorganisms, Russian Academy of Sciences, Pushchino, Moscow oblast, Russia.
Abstract:
An approach to developing an ecologically safe technology for disposal of yperite-lewisite mixtures has been developed. The technology includes three sequential stages: (1) detoxification by alkaline hydrolysis (resulting in the loss of toxic properties); (2) electrochemical treatment of detoxification products (electrocoagulation, to eliminate arsenic salts, and electrochemical oxidation, to convert all organic components into bioutilizable matter); and (3) degradation of the compounds obtained at the two preceding stages by a bred microbial association.

