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Synthesis of selected aminodeoxy analogs of globotriosylceramide
1Center for Chemistry and Chemical Engineering, Lund University, Sweden.
Carbohydrate Research
|January 19, 2000
Abstract:
Four aminodeoxy analogs of globotriosylceramide (6"-, 4"-, 2"-, and 6'-aminodeoxy) were synthesized by glycosylation of 3-O-benzoylated azidosphingosine with the corresponding aminodeoxy-globotriose trichloroacetimidate, followed by reduction of the azido group, N-acylation with 1-adamantaneacetic acid, and removal of the protecting groups.