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[Pt]
1Dipartimento di Chimica Inorganica, Metallorganica e Analitica e Centro CNR, Università di Milano, via G. Venezian 21, I-20133 Milano (Italy).
Angewandte Chemie (International Ed. in English)
|January 29, 2000
Abstract:
The intermediacy of CO/NO substitution in the condensation of [Pt(19)(CO)(22)](4-) into [Pt(38)(CO)(44)](2-) (structure shown) has been demonstrated. Two high-nuclearity carbonyl metal clusters, including one with an unprecedented nitrosyl ligand, have been synthesized and structurally characterized.