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Preparation and Use of Carbonyl-decorated Carbenes in the Activation of White Phosphorus
Published on: October 3, 2014
The Electrophilic Behavior of Stable Phosphanylcarbenes Towards Phosphorus Lone Pairs
Goumri-Magnet1, Polishchuk, Gornitzka
1Laboratoire d'Hétérochimie Fondamentale et Appliquée, Université Paul Sabatier, 118, route de Narbonne, F-31062 Toulouse cedex O4 (France).
Abstract:
As expected for a singlet carbene, the stable phosphanylsilylcarbene 1 possesses an accessible vacant orbital, as shown by reactions with Lewis bases such as phosphanes and a bimetallic complex containing a side-on-coordinated full blockC:full blockP identical withPfull blockC:full block moiety (see the reaction scheme). R=cHex(2)N.
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