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Thermoregulated Optical Properties of Peptidic Pseudorotaxanes

Meillon1, Voyer, Biron

  • 1Centre de recherche sur la fonction, la structure et l'ingénierie des protéines Département de chimie Faculté des sciences et de génie Pavillon A.-Vachon, Université Laval Québec, QC, G1K 7P4 (Canada).

Angewandte Chemie (International Ed. in English)
|January 29, 2000
PubMed

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It is essential to understand the difference between chiral and achiral interactions and the implications thereof in optical activity and their applications. Just as our feet, which are chiral, interact uniquely with chiral objects, such as a pair of shoes, but identically with achiral socks, enantiomers of a molecule exhibit different properties only when they interact with other chiral media. An example of a significant implication from this facet is the phenomenon known as optical activity,...