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Biotransformation of (4E,8R)-caryophyll-4(5)-en-8-ol by Botrytis cinerea
R Durán-Patrón1, J Aleu, R Hernández-Galán
1Departamento de Química Orgánica, Facultad de Ciencias, Universidad de Cádiz, Apdo. 40, 11510 Puerto Real, Cádiz, Spain.
Journal of Natural Products
|January 29, 2000
Abstract:
Biotransformation of (4E,8R)-caryophyll-4(5)-en-8-ol (1) with Botrytis cinerea afforded 14 products (3-16). Thirteen of these (4-16) are described here for the first time. The main reaction paths involved the isomerization of the double bond at C-4/C-5 and hydroxylation of methyl groups.