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New triterpenoid saponins and sapogenins from Saponaria officinalis

K Koike1, Z Jia, T Nikaido

  • 1Department of Pharmacognosy, School of Pharmaceutical Sciences, Toho University, Chiba, Japan.

Journal of Natural Products
|February 2, 2000
PubMed

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Esters to Carboxylic Acids: Saponification01:25

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Esters can be hydrolyzed to carboxylic acids under acidic or basic conditions. Base-promoted hydrolysis of esters is a nucleophilic acyl substitution reaction in which esters react with an aqueous base, followed by an acid to give carboxylic acids. This reaction is also known as saponification because it forms the basis for making soaps from fats.
The reaction requires a base in stoichiometric amounts, which participates in the reaction and is not regenerated later. So, the base acts as a...