Related Experiment Video
Updated: Aug 17, 2026

Synthesis of Cd-free InP/ZnS Quantum Dots Suitable for Biomedical Applications
Published on: February 6, 2016
Precipitation of Zinc Sulfide Particles from Homogeneous Solutions
1Chemical Engineering Department, Osaka Prefecture University, 1-1 Gakuencho, Sakai, 599-8531, Japan
Abstract:
Zinc sulfide particles were homogeneously precipitated by thermal decomposition of thioacetamide in acidic aqueous solutions in a one-step process. The influence of the operating conditions (initial concentration of zinc ion and TAA) on the nucleation time and number concentration of the generated particles was investigated. The experimental results show that the model of homogeneous nucleation previously developed and successfully tested for silver particle generation by a chemical reduction method can also be applied to the formation of zinc sulfide particles by homogeneous precipitation. Furthermore, in the particle formation method in which the nucleation time t* can be measured, the particle number concentration n* can be predicted by the simple relation n*=1/(4pir*Dt*) (r* is the critical nucleus radius, and D the monomer diffusion coefficient). Thus the particle number concentration can be easily predicted even if the rate expression and the critical supersaturation concentration are unknown. Copyright 2000 Academic Press.
More Related Videos
Related Concept Videos
Precipitation of Ions
The equation that describes the equilibrium between solid calcium carbonate and its solvated ions is:
Precipitate Formation and Particle Size Control
The obtained precipitate should be either a pure substance of known composition or easily converted to one by a simple process, such as ignition or drying. In addition, the precipitate should be insoluble and easily filterable. In general, filterability...
Precipitation Processes
Colloidal precipitates
Washing, Drying, and Ignition of Precipitates
Precipitation and Co-precipitation

