Rotational Spectrum of the AsH(2) Radical in Its Ground State, Studied by Far-Infrared Laser Magnetic Resonance

The rotational spectrum of AsH(2) in its ground &Xtilde;(2)B(1) electronic state has been recorded using a far-infrared laser magnetic resonance spectrometer. The AsH(2) radical was produced inside the spectrometer cavity by the reaction of arsine (AsH(3)) with fluorine atoms. Hyperfine splittings from both (75)As and (1)H nuclei were observed, and analysis of the spectra has yielded accurate values for rotational, hyperfine, and Zeeman parameters. Copyright 2000 Academic Press.