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Low (Sub-1-volt) halfwave voltage polymeric electro-optic modulators achieved by controlling chromophore shape

Shi1, Zhang, Zhang

  • 1TACAN Corporation, 2330 Faraday Avenue, Carlsbad, CA 92008, USA. Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, Los Angeles, CA 90089, USA. Center for Photonic Technologies, Department o.

Science (New York, N.Y.)
|February 7, 2001
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Summary

New organic chromophores significantly reduce drive voltages in electro-optic modulators. This advancement paves the way for next-generation telecommunications and information processing using polymeric materials.

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Area of Science:

  • Materials Science
  • Optoelectronics
  • Organic Chemistry

Background:

  • Electro-optic (EO) modulators are crucial for encoding electrical signals onto fiber optic transmissions.
  • High drive voltages in conventional polymeric and lithium niobate modulators limit performance by affecting gain and noise levels.
  • Existing modulators typically operate at halfwave voltages around 5 volts.

Purpose of the Study:

  • To develop novel organic chromophores that minimize intermolecular electrostatic interactions.
  • To fabricate EO modulators with significantly reduced halfwave voltages using these modified chromophores.
  • To explore the potential of advanced polymeric materials for high-performance optoelectronic devices.

Main Methods:

  • Steric modification of organic chromophores to reduce intermolecular electrostatic interactions.
  • Incorporation of modified chromophores into polymer hosts for EO modulator fabrication.
  • Utilizing optical push-pull poling and driving techniques to further decrease halfwave voltage.

Main Results:

  • Achieved EO modulators with a halfwave voltage of 0.8 volts at a 1318 nm telecommunications wavelength.
  • Demonstrated a halfwave voltage-interaction length product of 2.2 volt-centimeters.
  • Reported exceptional bandwidths exceeding 110 gigahertz and compatibility with semiconductor circuitry.

Conclusions:

  • Sterically modified organic chromophores offer a viable route to low-voltage EO modulators.
  • Polymeric materials show significant promise for next-generation telecommunications, information processing, and radio frequency distribution.
  • The developed modulators exhibit high performance, including low voltage and high bandwidth, suitable for advanced applications.