Related Experiment Video
Updated: Jul 25, 2026

Infrared Degenerate Four-wave Mixing with Upconversion Detection for Quantitative Gas Sensing
Published on: March 22, 2019
The Intensities of Methane in the 3-5 µm Region Revisited
1Laboratoire de Physique (Unité associée au C.N.R.S.), Université de Bourgogne, 9 Avenue A. Savary, Dijon, 21078, France
Abstract:
The analysis of the linestrengths of the infrared spectrum of methane (12 and 13) in the 3-5 µm region has been revisited on the basis of new measurements from Fourier transform spectra recorded at Kitt Peak under various optical densities. A simultaneous fit of these new data with previously reported tunable difference-frequency laser data has been done. An effective transition moment model in tensorial form up to the third order of approximation within the Pentad scheme has been used. The standard deviations achieved are very close to the experimental precision: 3 and 1.5%, respectively, for the two sets of data for the (12)CH(4) molecule, representing a substantial improvement with respect to earlier studies. The integrated bandstrengths obtained in the present work differ from previously reported values by factors ranging from -5 to +6%. The correction for the nu(3) band, the strongest band of the Pentad system, is +2% with respect to the study of Hilico et al. [J. C. Hilico, J. P. Champion, S. Toumi, V. G. Tyuterev, and S. A. Tashkun, J. Mol. Spectrosc. 168, 455-476 (1994)]. Copyright 2000 Academic Press.
Related Concept Videos
Inductive Effects on Chemical Shift: Overview
¹H NMR: Complex Splitting
Splitting diagrams or splitting tree diagrams are routinely used to depict such complex couplings. While drawing splitting diagrams, the splitting with the larger coupling constant is usually applied first.
Mass Spectrum
NMR Spectroscopy of Benzene Derivatives
¹H NMR Signal Integration: Overview
Spin–Spin Coupling Constant: Overview
Qualitatively, any spin plus-half nucleus polarizes the spins of its electrons to the minus-half state. Consequently, the paired electron in the hydrogen–carbon bond must have a...

