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Updated: Aug 1, 2026

Controlling the Size, Shape and Stability of Supramolecular Polymers in Water
Published on: August 2, 2012
Self-organization of spheroidal molecular assemblies in polar solvents
1Institut fur Organische Chemie und Makromolekulare Chemie, Heinrich-Heine-Universitat Dusseldorf, Germany.
Abstract:
[reaction: see text] We report a number of 1:1 noncovalent complexes composed of a symmetrical trisphosphonate and various symmetrical trisammonium or trisamidinium compounds. The spheroidal complexes show high thermodynamic stability, with association constants Ka reaching 10(6) M(-1) in methanol and in some cases even exceeding 10(3) M(-1) in water. The observed Ka values correlate well with the different degree of preorganization of the complexation partners.
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