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Tandem oxy-Cope/transannular ene reaction of 1,2-divinylcyclohexanols
1Department of Chemistry, University of Ottawa, Ontario, Canada.
Organic Letters
|May 18, 2000
Abstract:
[reaction: see text] The syntheses via tandem oxy-Cope/transannular ene reaction of 1,2-divinylcyclohexanols to bi- and tricyclic skeletons are described. This strategy generates a rapid method for the preparation of advanced polycyclic intermediates with high diastereoselectivity.