Related Experiment Videos
A new cryptand: synthesis and complexation with paraquat
W S Bryant1, J W Jones, P E Mason
1Department of Chemistry, Virginia Polytechnic Institute & State University, Blacksburg 24061, USA.
Organic Letters
|May 29, 2000
Abstract:
[formula: see text] Inspired by folded, nonpseudorotaxane complexes of bis(m-phenylene)-32-crown-10 systems, we synthesized a new bicyclic crown ether containing two 1,3,5-phenylene units linked by three tetra(ethyleneoxy) units. The new cryptand forms a "pseudorotaxane-like" inclusion complex with N,N'-dimethyl-4,4'-bipyridinium bis(hexafluorophosphate) with association constant Ka = 6.1 x 10(4) M-1, 100-fold greater than that of an analogous simple crown ether.