Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Videos

Through-bond connectivity in solids by continuous-wave spin lock.

P Hartmann1, J W Zwanziger, C Jäger

  • 1Institut für Optik und Quantenelektronik, Friedrich-Schiller Universität Jena, Germany. p5peha@uni-jena.de

Solid State Nuclear Magnetic Resonance
|June 27, 2000
PubMed
Summary
This summary is machine-generated.

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Robotic resection of a rudimentary horn pregnancy with the Da Vinci system: first case and systematic review of published cases in the 21st century.

Frontiers in surgery·2026
Same author

J couplings in the solid state from direct energy computations.

Solid state nuclear magnetic resonance·2025
Same author

Caseload, clinical spectrum and economic burden of infectious diseases in patients discharged from hospitals in Germany.

Infection·2025
Same author

Relativistic effects on the magnetic shielding in solids: First-principles computation in a plane wave code.

Journal of magnetic resonance (San Diego, Calif. : 1997)·2025
Same author

Evoked responses to rhythmic visual stimulation vary across sources of intrinsic alpha activity in humans.

Scientific reports·2022
Same author

Association of bacteria in pancreatic fistula fluid with complications after pancreatic surgery.

BJS open·2020
Same journal

Experimental and computational <sup>11</sup>B NMR comparative study of MOVPE-grown rhombohedral and bulk hexagonal boron nitride.

Solid state nuclear magnetic resonance·2026
Same journal

Determination of <sup>137</sup>Ba nuclear quadrupole interactions in solids: a comparison of high field and zero field approaches.

Solid state nuclear magnetic resonance·2026
Same journal

Probing interlayer bromide in solvent intercalation of layered yttrium hydroxide via <sup>79/81</sup>Br SSNMR spectroscopy.

Solid state nuclear magnetic resonance·2026
Same journal

Single crystal sapphire spacers for in situ angle sensing and rotor stability diagnostics in MAS NMR.

Solid state nuclear magnetic resonance·2026
Same journal

Insights into the local adsorption of CO<sub>2</sub> in UiO-66.

Solid state nuclear magnetic resonance·2026
Same journal

<sup>75</sup>As NQR characterisation of cobaltite (CoAsS).

Solid state nuclear magnetic resonance·2026
See all related articles

A novel two-dimensional correlation experiment under fast magic angle spinning (MAS) enables solid-state through-bond connectivity determination. This method leverages isotropic J-coupling, similar to TOCSY, for magnetization transfer in materials science.

Area of Science:

  • Solid-state Nuclear Magnetic Resonance (NMR) Spectroscopy
  • Materials Science
  • Physical Chemistry

Background:

  • Determining through-bond connectivity is crucial for solid-state structure elucidation.
  • Traditional methods can be complex or limited in scope.
  • Fast magic angle spinning (MAS) offers enhanced spectral resolution in solid-state NMR.

Purpose of the Study:

  • To introduce a simple 2D correlation NMR experiment for solid-state through-bond connectivity.
  • To demonstrate the utility of isotropic J-coupling under MAS conditions.
  • To investigate the mixing-time dependence of magnetization exchange rates.

Main Methods:

  • Implementation of a 2D correlation experiment with fast MAS.
  • Utilizing a spin-locking pulse for mixing after free evolution under the MAS Hamiltonian.

Related Experiment Videos

  • Exploiting the dominance of isotropic J-coupling under strong spin-locking conditions.

    • Main Results:

    • The developed experiment effectively determines through-bond connectivity in the solid state.
    • The mixing Hamiltonian resembles the Total Correlation Spectroscopy (TOCSY) Hamiltonian, enabling magnetization transfer.
    • Demonstrated applications on crystalline P4S7 and MgP4O11.

    Conclusions:

    • The described 2D correlation experiment provides a straightforward approach for solid-state through-bond analysis.
    • This method is valuable for structural characterization of solid materials.
    • The technique highlights the importance of J-coupling under MAS and spin-locking conditions.