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Updated: Aug 5, 2026

Amide Coupling Reaction for the Synthesis of Bispyridine-based Ligands and Their Complexation to Platinum as Dinuclear Anticancer Agents
Published on: May 28, 2014
Platinum-catalyzed diboration using a commercially available catalyst: diboration of aldimines to alpha-aminoboronate
1Los Alamos Catalysis Initiative, Chemistry Division, Los Alamos National Laboratory, MS J514, Los Alamos, New Mexico 87545, USA.
Abstract:
Commercially available Pt(cod)Cl(2) catalyzes the diboration of alkenes, alkynes, and aldimines using bis(catecholato)diboron (cod = 1,5-cyclooctadiene). Catalyzed aldimine diboration provides the first direct route to alpha-aminoboronate esters. The diboration product from N-benzylidene-2,6-dimethylaniline is structurally characterized.
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