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Updated: Oct 13, 2026
![[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
(Benzoylacetonato)chloro(1,10-phenanthroline)copper(II)
1Department of Engineering Physics, Faculty of Sciences, University of Ankara, 06100 Besevler, Ankara, Turkey. elerman@science.ankara. edu.tr.
Abstract:
The crystal structure of the title compound, chloro(1, 10-phenanthroline-N,N')(1-phenyl-1,3-butanedionato-O,O')copper(II), [CuCl(C(10)H(9)O(2))(C(12)H(8)N(2))], has been determined. The Cu(II) ion displays a distorted square-pyramidal coordination, being linked to the two O atoms of the benzoylacetonate ligand and the two N atoms of the 1,10-phenanthroline ligand in the basal plane, and the Cl atom in the apical site. TheCu-N, Cu-O and Cu-Cl bond lengths are 2.043 (2)/2.025 (2), 1.914 (2)/1.941 (2) and 2.485 (1) A, respectively.
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