Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Videos

O-Isopropyl N-(2-furoyl)thiocarbamate

Morales1, Novoa De Armas H, Blaton

  • 1Quimica Analitica, Centro de Investigaciones del Petroleo, Washington No. 169 Esquina a Churruca, Cerro, Codigo Postal 12000, Apartado Postal 167, Ciudad de la Habana, Cuba.

Acta Crystallographica. Section C, Crystal Structure Communications
|August 16, 2000
PubMed
Summary

This study details the crystallographic structure of a novel thiocarbamate compound, C(9)H(11)NO(3)S. The research reveals its unique molecular conformation and intramolecular hydrogen bonding, crucial for understanding its chemical properties.

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Hormonal treatment of agalactia in the mare.

The Veterinary record·2010
Same author

Immunosuppression in pancreas transplantation: the Euro SPK trials and beyond.

Acta chirurgica Belgica·2009
Same author

Ex utero intrapartum treatment (EXIT), a resuscitation option for intra-thoracic foetal pathologies.

Swiss medical weekly·2007
Same author

Protective Effect of Broccoli, Onion, Carrot, and Licorice Extracts against Cytotoxicity of N-Nitrosamines Evaluated by 3-(4,5-Dimethylthiazol-2-yl)-2,5-diphenyltetrazolium Bromide Assay.

Journal of agricultural and food chemistry·2001
Same author

A DFT theoretical analysis of aldehyde condensation pathways onto methyllithium, lithium dimethylamide, and their aggregates

The Journal of organic chemistry·2001
Same author

Atomic Structure of the Stoichiometric GaAs(114) Surface.

Physical review letters·2001

Area of Science:

  • Crystallography
  • Organic Chemistry
  • Molecular Structure

Background:

  • Understanding the three-dimensional structure of organic compounds is fundamental in chemistry.
  • Thiocarbamates represent a class of compounds with diverse applications, necessitating detailed structural analysis.

Purpose of the Study:

  • To elucidate the crystallographic structure and molecular conformation of the title compound, C(9)H(11)NO(3)S.
  • To identify and characterize intramolecular hydrogen bonding interactions within the molecule.
  • To investigate the intermolecular forces governing crystal packing.

Main Methods:

  • Single-crystal X-ray diffraction was employed to determine the precise atomic arrangement.
  • Analysis of bond lengths, bond angles, and torsion angles defined the molecular geometry.

Related Experiment Videos

  • Intermolecular interactions, including van der Waals forces, were inferred from the crystal packing.

    • Main Results:

    • The compound C(9)H(11)NO(3)S exhibits crystallographic mirror symmetry.
    • The molecule adopts a thiocarbamate form stabilized in an s-cisoid,s-transoid conformation.
    • Two significant intramolecular hydrogen bonds were identified: N-H···O (furan) and C-H···S.

    Conclusions:

    • The determined structure provides critical insights into the stability and reactivity of this thiocarbamate.
    • The identified hydrogen bonds play a key role in stabilizing the observed molecular conformation.
    • Van der Waals interactions are presumed to be the primary drivers of the observed crystal packing.