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Quenching of giant hysteresis effects in La(1-z)Y(z)Hx switchable mirrors
van Gogh AT1, Nagengast, Kooij
1Faculty of Sciences, Division of Physics and Astronomy, Vrije Universiteit, De Boelelaan 1081, 1081 HV Amsterdam, The Netherlands.
Abstract:
The giant intrinsic hysteresis as a function of hydrogen concentration x in the optical and electrical properties of the archetypal switchable mirror YHx is eliminated by alloying Y with the chemically similar La. The La(1-z)Y(z)Hx films with z=0.67 are essentially hysteresis-free. The origin of the large hysteresis of alloys with z>/=0.86 is the large uniaxial lattice expansion that accompanies their fcc to hexagonal phase transition in combination with lateral clamping.
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