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High-Resolution Fourier Transform Emission Spectroscopy of the TiCl Radical in the 420-nm Region
1Department of Chemistry, Faculty of Science, Kyushu University 33, Hakozaki, Higashiku, Fukuoka, 812-8581, Japan
Journal of Molecular Spectroscopy
|September 15, 2000
Abstract:
Emission spectra of the TiCl radical in the 420-nm region have been observed at a resolution of 0.04 cm(-1) using a Fourier transform spectrometer. A new electronic assignment of (4)Gamma-X(4)Phi has been proposed. Rotational analysis has been provided for the 0-0 and 1-1 vibrational bands of the (4)Gamma(5/2)-X(4)Phi(3/2) and (4)Gamma(7/2)-X(4)Phi(5/2) spin components and the 0-0 band of (4)Gamma(9/2)-X(4)Phi(7/2). Copyright 2000 Academic Press.