Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Videos

[H3N]

Phan Thanh S1, Marrot, Renaudin

  • 1Laboratoire des Fluorures - UPRES-A 6010 Faculte des Sciences, Universite du Maine, Avenue Olivier-Messiaen, 72085 Le Mans CEDEX 9, France.

Acta Crystallographica. Section C, Crystal Structure Communications
|September 15, 2000
PubMed
Summary

Researchers synthesized pentane-1,5-diammonium aluminium(III) hydrogen bis(phosphate) using solvothermal methods. The crystal structure reveals one-dimensional macroanions linked by hydrogen bonds, forming a unique 3D network.

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Extraction of a Foreign Body Implanted in the Uterus.

Western journal of medicine and surgery·2024
Same author

A New Method of Reducing Dislocations of the Elbow Joint Backwards.

Western journal of medicine and surgery·2024
Same author

Tetraaquabis(3,5-dicarboxybenzoato-O)cobalt(II)

Acta crystallographica. Section C, Crystal structure communications·2000
Same author

Peer review in health sciences

BMJ (Clinical research ed.)·2000
Same author

Synthesis, Crystal Structure, and Magnetic Behavior of Linear MU(IV) Complexes (M=Co, Ni, Cu, Zn).

Angewandte Chemie (International ed. in English)·2000
Same author

Effects of yoghurt intake on plasmid transfer and colonisation with transconjugants in the digestive tract of mice associated with human faecal flora.

FEMS microbiology ecology·2000

Area of Science:

  • Materials Science
  • Inorganic Chemistry
  • Crystallography

Background:

  • Metal phosphates are known for diverse structural motifs.
  • Hydrogen bonding plays a crucial role in supramolecular assembly.
  • Solvothermal synthesis offers a route to novel crystalline materials.

Purpose of the Study:

  • To determine the crystal structure of pentane-1,5-diammonium aluminium(III) hydrogen bis(phosphate).
  • To investigate the self-assembly mechanism of the compound.
  • To explore the role of hydrogen bonding in structure formation.

Main Methods:

  • Single-crystal X-ray diffraction was employed for structural determination.
  • Solvothermal synthesis at 473 K was used for material preparation.
  • Analysis of intermolecular interactions, particularly hydrogen bonds, was performed.

Main Results:

  • The compound crystallizes as one-dimensional [AlP(2)O(8)H](2-) macroanions.
  • Pentanediammonium cations act as linkers between the anionic chains.
  • A significant hydrogen bond network dictates the three-dimensional structure, unlike related compounds.

Conclusions:

  • The crystal structure of pentane-1,5-diammonium aluminium(III) hydrogen bis(phosphate) was elucidated.
  • Hydrogen bonding is the primary driving force for the 3D network formation.
  • This study highlights the importance of cation-anion interactions in designing novel inorganic-organic hybrid materials.

Related Experiment Videos