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NMR probe of phase segregation in electron doped mixed valence manganites

Kapusta1, Riedi, Sikora

  • 1Department of Solid State Physics, Faculty of Physics and Nuclear Techniques, University of Mining and Metallurgy, 30-059 Cracow, Poland and and Department of Physics and Astronomy, University of St. Andrews, St. Andrews, Fife, KY16 9SS, Scotlan.

Physical Review Letters
|September 16, 2000
PubMed

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¹H NMR: Complex Splitting01:13

¹H NMR: Complex Splitting

A proton M that is coupled to a proton X results in doublet signals for M. However, NMR-active nuclei can be simultaneously coupled to more than one nonequivalent nucleus. When M is coupled to a second proton A, such as in styrene oxide, each peak in the doublet is split into another doublet.
Splitting diagrams or splitting tree diagrams are routinely used to depict such complex couplings. While drawing splitting diagrams, the splitting with the larger coupling constant is usually applied first.