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Multifrequency EPR spectra of molecular oxygen in solid Air
1Istituto di Fisica Atomica e Molecolare, National Research Council, S. Cataldo, Pisa, 56100, Italy.
Abstract:
Multifrequency EPR spectra in the 94 to 550 GHz range were performed on solid air samples condensed at 5 K in the waveguide of a single pass probe. The spectra of molecular oxygen were observed and interpreted in the frame of the spin Hamiltonian model as axial S = 1 spectra with a zero field splitting parameter D = 3.572(3) cm(-1). The result of this study is relevant in the field of high field-high frequency EPR application in which solid air O(2) is a common paramagnetic impurity. Copyright 2000 Academic Press.
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