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Updated: Oct 11, 2026

Orientational Transition in a Liquid Crystal Triggered by the Thermodynamic Growth of Interfacial Wetting Sheets
Published on: May 15, 2017
Orientational dynamics in supercooled liquids near T(c) and comparison with ideal mode-coupling theory
1Department of Chemistry, Stanford University, Stanford, California 94305, USA.
Abstract:
Orientational dynamics in supercooled salol and ortho-terphenyl were measured near their critical temperatures, T(c), with optical Kerr effect experiments spanning a very broad range of times. Above T(c), the decays are shown to be in excellent agreement with the master curve predicted by ideal mode-coupling theory when higher order terms are included. Between the critical decay and the von Schweidler power laws, the intermediate time range of the data can be modeled by a power law. This intermediate power law, located at 2
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