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Updated: Aug 12, 2026
![Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F51444.jpg&w=3840&q=50)
Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
Published on: March 20, 2014
trans-Dichloro(1,12-diphenyl-5,8-dioxa-2,11-dithiadodecane-S, S')palladium(II)
1Research Institute of Natural Sciences, Gyeongsang National University, Chinju 660-701, South Korea.
Abstract:
In the title compound, [PdCl(2)(C(20)H(26)O(2)S(2))], the Pd atom has a distorted square-planar coordination geometry, with Pd-S distances of 2.3121 (18) and 2.3102 (18) A, Pd-Cl distances of 2.291 (2) and 2.314 (2) A, and S-Pd-Cl angles of 94.98 (7) and 86.25 (7) degrees. Upon complexation, an 11-membered ring is formed by the S-Pd-S linkage in the ligand chain.
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