Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

Disubstituted Cyclohexanes: cis-trans Isomerism02:37

Disubstituted Cyclohexanes: cis-trans Isomerism

14.8K
Depending upon the different spatial orientation of the substituents, the disubstituted cycloalkanes exhibit two types of stereoisomers. The cis isomers have the substituents on the same side of the ring, whereas the trans isomers have the substituents on the opposite sides. These stereoisomers exhibit different physical properties and cannot be interconverted without breaking the carbon-carbon bonds.
In cyclohexane, the substituents can occupy different positions generating distinct isomers....
14.8K
Stability of Conjugated Dienes01:28

Stability of Conjugated Dienes

4.6K
Introduction
A comparison of the enthalpies of hydrogenation of dienes reveals that conjugated dienes release less heat on hydrogenation, rendering them more stable than their nonconjugated analogs.
4.6K
Benzene to 1,4-Cyclohexadiene: Birch Reduction Mechanism01:18

Benzene to 1,4-Cyclohexadiene: Birch Reduction Mechanism

2.7K
Birch reduction uses solvated electrons as reducing agents. The reaction converts benzene to 1,4-cyclohexadiene. The reaction proceeds by the transfer of a single electron to the ring to form a benzene radical anion. This anion is highly basic—it abstracts a proton from the alcohol to form a cyclohexadienyl radical. Another single electron transfer gives the cyclohexadienyl anion. A proton transfer from the alcohol forms 1,4-cyclohexadiene. Since this reduction occurs via radical anion...
2.7K
Diels–Alder Reaction Forming Bridged Bicyclic Products: Stereochemistry01:29

Diels–Alder Reaction Forming Bridged Bicyclic Products: Stereochemistry

6.2K
Diels–Alder reactions between cyclic dienes locked in an s-cis configuration and dienophiles yield bridged bicyclic products.
6.2K
Diels–Alder Reaction Forming Cyclic Products: Stereochemistry01:28

Diels–Alder Reaction Forming Cyclic Products: Stereochemistry

5.2K
The Diels–Alder reaction is one of the robust methods for synthesizing unsaturated six-membered rings. The reaction involves a concerted cyclic movement of six π electrons: four π electrons from the diene and two π electrons from the dienophile.
5.2K
Diazonium Group Substitution with Halogens and Cyanide: Sandmeyer and Schiemann Reactions01:20

Diazonium Group Substitution with Halogens and Cyanide: Sandmeyer and Schiemann Reactions

2.6K
Arenediazonium substitution reactions occur when the diazonium group is substituted by various functional groups such as halides, hydroxyl, nitrile, etc. For instance, arenediazonium salts react with copper(I) salts of chloride, bromide, or cyanide to form corresponding aryl chlorides, bromides, and nitriles. These reactions are named Sandmeyer reactions. Although the mechanism of this reaction is complicated, as illustrated in Figure 1, they are believed to progress via an aryl copper...
2.6K

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

A donor-acceptor compound composed of a dinuclear zinc(II) complex of a robson macrocycle with 8-methylquinoline

Acta crystallographica. Section C, Crystal structure communications·2000
Same author

Ferromagnetic Ordering in a Two-Dimensional Copper Complex with Dual End-to-End and End-On Azide Bridges This work was supported by the National Natural Science Foundation of China (NSF 29631040 and 29929001), The Major State Basic Research Development Program (Grant No. G2000077500 and No. G1998061306), and the Malaysian Government research grant R&D No. 305/pfizik/622004.

Angewandte Chemie (International ed. in English)·2000
Same author

4-(N-Hydroxyethyl-N-methylamino)benzaldehyde thiosemicarbazone

Acta crystallographica. Section C, Crystal structure communications·2000
Same author

Two benzoylaminoacridinedione derivatives

Acta crystallographica. Section C, Crystal structure communications·2000
Same author

2-(Nitromethylene)-1,3-dithietane

Acta crystallographica. Section C, Crystal structure communications·2000
Same author

(N,N-Diisopropyldithiocarbamato-S, S')bis(triphenylphosphine-P)gold(I) butane solvate

Acta crystallographica. Section C, Crystal structure communications·2000

Related Experiment Video

Updated: Mar 1, 2026

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
10:44

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals

Published on: April 19, 2019

11.7K

trans-cis S-benzyl dithiocarbazate

Shanmuga Sundara Raj S1, Yamin, Yussof

  • 1X-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia.

Acta Crystallographica. Section C, Crystal Structure Communications
|October 12, 2000
PubMed
Summary

This study reveals the crystal structure of C(8)H(10)N(2)S(2), detailing how molecules link via N-H.S hydrogen bonds. These bonds form chains along the b axis, with a specific rotation observed between the dithiocarbazate and phenyl groups.

More Related Videos

Synthesis and Bioconjugation of Thiol-Reactive Reagents for the Creation of Site-Selectively Modified Immunoconjugates
08:47

Synthesis and Bioconjugation of Thiol-Reactive Reagents for the Creation of Site-Selectively Modified Immunoconjugates

Published on: March 6, 2019

10.2K
Scale-up Chemical Synthesis of Thermally-activated Delayed Fluorescence Emitters Based on the Dibenzothiophene-S,S-Dioxide Core
08:51

Scale-up Chemical Synthesis of Thermally-activated Delayed Fluorescence Emitters Based on the Dibenzothiophene-S,S-Dioxide Core

Published on: October 24, 2017

10.2K

Related Experiment Videos

Last Updated: Mar 1, 2026

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
10:44

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals

Published on: April 19, 2019

11.7K
Synthesis and Bioconjugation of Thiol-Reactive Reagents for the Creation of Site-Selectively Modified Immunoconjugates
08:47

Synthesis and Bioconjugation of Thiol-Reactive Reagents for the Creation of Site-Selectively Modified Immunoconjugates

Published on: March 6, 2019

10.2K
Scale-up Chemical Synthesis of Thermally-activated Delayed Fluorescence Emitters Based on the Dibenzothiophene-S,S-Dioxide Core
08:51

Scale-up Chemical Synthesis of Thermally-activated Delayed Fluorescence Emitters Based on the Dibenzothiophene-S,S-Dioxide Core

Published on: October 24, 2017

10.2K

Area of Science:

  • Crystallography
  • Chemical Physics
  • Materials Science

Background:

  • Understanding molecular interactions is crucial for predicting material properties.
  • Hydrogen bonding plays a significant role in the self-assembly of organic molecules.
  • The structural characterization of novel organic compounds provides fundamental insights into chemical bonding and intermolecular forces.

Purpose of the Study:

  • To elucidate the crystal structure of the title compound, C(8)H(10)N(2)S(2).
  • To investigate the intermolecular interactions, specifically hydrogen bonding, within the crystal lattice.
  • To determine the conformational preferences of the dithiocarbazate moiety relative to the phenyl ring.

Main Methods:

  • Single-crystal X-ray diffraction was employed to determine the three-dimensional structure.
  • The crystal structure was solved and refined using standard crystallographic techniques.
  • Intermolecular interactions, including hydrogen bonds, were analyzed based on atomic coordinates.

Main Results:

  • The crystal structure of C(8)H(10)N(2)S(2) was successfully determined.
  • Molecules are interconnected by N-H...S hydrogen bonds, forming infinite chains along the b crystallographic axis.
  • A significant dihedral angle of 85.8 (2) degrees was observed between the dithiocarbazate group and the phenyl ring.

Conclusions:

  • The N-H...S hydrogen bonding network dictates the observed chain-like assembly in the crystal structure.
  • The conformational analysis reveals a near-orthogonal relationship between the dithiocarbazate and phenyl moieties.
  • This structural data provides a foundation for understanding the physical and chemical properties of this class of compounds.