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Updated: Oct 11, 2026

Fluid-cell Raman Spectroscopy for operando Studies of Reaction and Transport Phenomena during Silicate Glass Corrosion
Published on: May 9, 2025
Simple views on critical binary liquid mixtures in porous glass
1Departement de Chimie, Universite de Sherbrooke, Sherbrooke, Quebec, Canada J1K 2R1.
Abstract:
A simple scenario, different from previous attempts, is proposed to resolve the problem of the slow phase separation dynamics of binary liquid mixtures confined in porous Vycor glass. We demonstrate that simply mutual diffusion, renormalized by critical composition fluctuations and geometrical hindrance of the porous glass, accounts for the slow phase separation kinetics. Capillary invasion studies of porous Vycor glass by the critical isobutyric acid-water mixture, close to the consolute solution temperature, corroborate our analysis.
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