Related Experiment Video
Updated: Oct 11, 2026

High-Resolution Neutron Spectroscopy to Study Picosecond-Nanosecond Dynamics of Proteins and Hydration Water
Published on: April 28, 2022
Heterogeneous relaxation patterns in supercooled liquids studied by solvation dynamics
Abstract:
We have measured the solvation dynamics of a dipolar supercooled liquid near its glass transition in a temperature range in which the average structural relaxation time varies more than four orders of magnitude. The analysis of the time dependent average emission energy and the inhomogeneous linewidth of the S0<--T1(0-0) transition reveals that the orientation correlation decay pattern intrinsic in each relaxing unit is associated with a stretching exponent beta(intr)=1.00+/-0.08 in the entire range T(g)=T=T(g)+6 K. Our analysis also allows one to detect fluctuations in terms of the resulting apparent homogeneity within the long time tail of the decay. Even at times significantly exceeding the average structural relaxation time, no sign of a transition towards purely exponential or otherwise homogeneous behavior could be observed. This implies that even at t approximately 50
More Related Videos
09:25NMR 15N Relaxation Experiments for the Investigation of Picosecond to Nanoseconds Structural Dynamics of Proteins
Published on: November 1, 2024
11:38Combining Microfluidics and Microrheology to Determine Rheological Properties of Soft Matter during Repeated Phase Transitions
Published on: April 19, 2018
Related Concept Videos
Atomic Nuclei: Types of Nuclear Relaxation
In spin–lattice or longitudinal relaxation, the excited spins exchange energy with the surrounding lattice as they return to the lower energy level. Among several mechanisms that contribute to spin–lattice relaxation, magnetic dipolar interactions are significant. Here, the excited nucleus transfers energy to a nearby...
Entropy and Solvation
Chemical Shift: Internal References and Solvent Effects
The internal reference compound generally used in NMR spectroscopy is tetramethylsilane (TMS). TMS is preferred because it is chemically inert, soluble in NMR solvents, and easily removable. Also, the highly shielded methyl protons in TMS yield an intense...
¹H NMR of Conformationally Flexible Molecules: Temporal Resolution
Solubility Equilibria: Overview
Solubility is important in biological and environmental processes. A notable...
Molecular and Ionic Solids
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...