Tris(2,6-di-tert-butyl-4-methylphenolato-O)(triphenylphosphine oxide-O)samarium(III)
1Department of Chemistry, Suzhou University, Suzhou 215006, People's Republic of China.
Acta Crystallographica. Section C, Crystal Structure Communications
|November 15, 2000
Abstract:
In the title complex, [Sm(C(15)H(23)O)(3)(C(18)H(15)OP)], the central metal atom is coordinated by three O atoms of the aryloxo ligands and by one O atom of the triphenylphosphine oxide molecule resulting in a distorted tetrahedral geometry. The Sm-O(Ar) distances (Ar is aryl) range from 2.122 (2) to 2.190 (2) A and the Sm-O(PPh(3)) bond length is 2.306 (2) A.


