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Published on: January 9, 2014
Fluid of penetrable spheres: testing the universality of the bridge functional
Abstract:
Penetrable spheres have been the object of recent extensive investigations as a prototype for intermicellar interactions in a solvent, and as representing a class of bounded potentials allowing complete interpenetrability of the particles. Here we compare density-functional and simulation results for the pair-correlation functions in a bulk fluid of penetrable spheres, as a stringent test for the approximation of "universality" of the bridge functional. Considering either a fundamental-measure functional for penetrable spheres or a perturbative treatment using a fundamental-measure hard-sphere functional, we conclude that hard-sphere-type bridge functionals are applicable also for bounded potentials with high penetrability.
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