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Crespo1, Gimeno, Jones

  • 1Departamento de Quimica Inorganica, Universidad de Zaragoza-CSIC, Instituto de Ciencia de Materiales de Aragon, 50009 Zaragoza, Spain.

Acta Crystallographica. Section C, Crystal Structure Communications
|December 19, 2000
PubMed
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This study details the structure of a gold-ferrocene complex, [Au(2)Cl(2)Fe(C(17)H(14)P)(2)], highlighting its linear gold centers and bridging ferrocene ligand. The findings offer insights into organometallic compound structures.

Area of Science:

  • Organometallic Chemistry
  • Coordination Chemistry
  • Materials Science

Background:

  • Ferrocene derivatives are versatile ligands in organometallic chemistry.
  • Gold complexes with phosphorus ligands exhibit interesting structural and electronic properties.
  • Bridging ligands can create unique multinuclear metal centers.

Purpose of the Study:

  • To characterize the crystal structure of the novel gold-ferrocene complex, [Au(2)Cl(2)Fe(C(17)H(14)P)(2)].
  • To investigate the coordination behavior of a ferrocene moiety acting as a P, P'-bridging ligand.
  • To compare the structural features with related gold-ferrocene compounds.

Main Methods:

  • Single-crystal X-ray diffraction analysis was employed to determine the molecular structure.

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  • The crystal structure revealed linear gold centers and a bridging ferrocene unit.
  • Key bond angles (P-Au-Cl) and distances (Au-P, Au-Cl) were precisely measured.

    • Main Results:

    • The compound [Au(2)Cl(2)Fe(C(17)H(14)P)(2)] features linear gold centers as expected.
    • The iron atom of the ferrocene moiety is located on an inversion center, acting as a P, P'-bridging ligand.
    • The determined structure closely resembles a previously reported complex but differs significantly from another, particularly regarding intermolecular Au-Au interactions.

    Conclusions:

    • The ferrocene unit effectively bridges two gold centers, forming a unique organometallic framework.
    • The structural data provides valuable information for understanding ligand design in gold-ferrocene chemistry.
    • Comparison with related structures highlights the subtle influence of crystal packing and intermolecular forces on molecular geometry.