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Orientational Transition in a Liquid Crystal Triggered by the Thermodynamic Growth of Interfacial Wetting Sheets
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Freedericksz transition in an anticlinic liquid crystal

Wen1, Zhang, Keast

  • 1Department of Physics, Case Western Reserve University, Cleveland, Ohio 44106, USA.

Physical Review. E, Statistical Physics, Plasmas, Fluids, and Related Interdisciplinary Topics
|January 4, 2001
PubMed
Summary

Surface-stabilized anticlinic liquid crystals show a two-step electric-field transition to the synclinic phase. This study details the Freedericksz transition and its temperature dependence, observing quenched fluctuations and solitary wave transitions.

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Area of Science:

  • Materials Science
  • Condensed Matter Physics
  • Liquid Crystal Physics

Background:

  • Anticlinic liquid crystals exhibit unique phase behaviors under external stimuli.
  • The Freedericksz transition is a fundamental phenomenon in liquid crystal physics.
  • Understanding electric-field-induced transitions is crucial for display technologies and advanced materials.

Purpose of the Study:

  • To experimentally investigate the electric-field-induced phase transitions in very-long-pitch, surface-stabilized, anticlinic liquid crystals.
  • To characterize the Freedericksz transition and its dependence on temperature.
  • To explore the behavior of acoustic Goldstone mode fluctuations and the high-field transition to the synclinic phase.

Main Methods:

  • Utilizing the Freedericksz geometry for experimental analysis.
  • Measuring the threshold electric field (E(th)) as a function of temperature.
  • Employing quasielastic light scattering to study acoustic Goldstone mode fluctuations.

Main Results:

  • A two-step electric-field-induced transition from the anticlinic to the synclinic phase was observed.
  • The Freedericksz transition, involving unequal azimuthal rotations in smectic layers, was characterized.
  • Acoustic Goldstone mode fluctuations were found to be quenched by a DC electric field above E(th).
  • A transition to the synclinic phase via solitary waves was observed at high electric fields.

Conclusions:

  • The study elucidates the complex electric-field-induced phase transitions in anticlinic liquid crystals.
  • The findings provide insights into the fundamental physics governing these materials.
  • This research contributes to the understanding of liquid crystal behavior for potential applications.